There's many ways to go if you are a level 85 PvP Rogue, if you are 85, I would say stick with the most common spec with Subtlety, and make new hot keys, level 85 poison use:
Main-hand : Mind Numbing Poison
Off-hand : Crippling Poison
As for twink rogues ( 19, 29, 39, ect.), I would recommend going as a combat spec, while holding either two swords, or a sword in the main-hand, and dagger for off-hand. As for poison, it should go something like this:
Main-hand : Deadly Poison
Off-hand : Crippling Poison
This guide is for a level 19 twink, if this isn't helpful. just find a simple guide in google:
http://www.wowwiki.com/Level_19_rogue_twinking_guide
Try reading this place for PvP tips as a level 85 rogue: ( This is one of the best )
http://www.arenajunkies.com/
Hope This Info Helps! Have Fun in the Game!!!!!
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