The haste buff herbalism will give you is important. You can place this in a macro with your boss cooldowns. Alchemy is always a plus, you get potions, 2 hour flasks, the works. What isn't there to love? I would go with herbalism, alchemy as a caster. Although Alchemy by itself won't actually benefit you without the potions/flasks herbalism will. Hope this helped you make up your mind. I have herbalism on both my casting toons.
Also, tailoring has the most intellect from any profession. It is, however, a proc. Lightweave Embroidery gives 570 intellect for 15 seconds with a 20% proc rate on spellcast. It has a 50 second cooldown.
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