To answer you first question, the best PvE spec can be any spec, marksman, beast mastery or survival. It's all up to which style you feel most comfortable playing. If you like laying out traps and such, survival is nice, or if you prefer to nuke your enemies with shots, markmanship is awesome. The spec i play love to play in for PvE is marksman because it's simple to use.
To answer your second question, The rotation for MM hunters goes as follows:
We no longer have any kind of fixed MM rotation, instead firing our shots in a priority system and making decisions as we play about whether to save up focus for the MM signature shot, or to burn focus before it caps out.
And thirdly, any cat/wolf pet is fine for dps. Such as the the little blue dog in the borean tundra.
Well that's all, hope i helped!
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